In Vyatka, as an exile, Andriolli quickly took up portraying the local inhabitants; he also did some minor conservation work and painted iconostases for Orthodox churches in several nearby villages. There, he became the teacher of the then 12-year-old Anna Bilińska, the daughter of a doctor practising in Vyatka, and soon an outstanding painter. He also started to cooperate with Tygodnik Ilustrowany, sending illustrations to the poetic texts published there. In 1871, he regained his freedom, left for Warsaw and started to work with several other illustrated periodicals – including Kłosy, Wędrowiec and Tygodnik Powszechny.
Andriolli made up for almost a decade spent on wandering, hiding, and finally in exile by working extra hard, and the centre of gravity of his art shifted from painting to illustration. At that time Wojciech Gerson, Franciszek Kostrzewski and Ksawery Pillati also worked in Polish periodicals as illustrators, but they were also active in other fields, which meant that they were present in the press less often. Concentrating fully on his illustration activities, Andriolli soon became a leading figure in this market.
A series of illustrations by Andriolli to Antoni Malczewski’s Maria was reproduced in Poland using a new technique – in the form of photographic prints of large-format crayon drawings. After some time it proved not to be very durable; the photographs faded quickly. Much more durable was the dominant, at that time, woodcut illustration, in which the artist’s drawing, usually applied directly onto a primed wooden block, from which the matrix was made, was already prepared for printing by a wood engraver interpreting the artist’s composition. In the case of less-skilled craftsmen, there was a risk of simplification and distortion of the original composition. Although Andriolli sometimes complained about it, the beginning of his career turned out to be a string of successes. He worked a lot and earned a lot, and soon he bought a small brick manor house in Stasinowo near Warsaw (today in Mińsk Mazowiecki).