The Polish woman agreed to take over her husband’s duties at the university and was therefore given a professorial chair. This was also a historic event, as she became the first woman to lecture at the Sorbonne, first as an associate professor and from 1908 as a full professor. Crowds had been waiting for her first lecture on 5th November 1906 since early morning. When Skłodowska-Curie appeared in the auditorium, she was greeted by a storm of applause, but she, showing no emotion, in a cool and matter-of-fact tone, began her lecture where Pierre Curie had left off.
In 1910, Curie’s father-in-law died, which was another blow and a difficulty in balancing family life and work. She placed great importance on the upbringing of her daughters, their education, and physical activity, which she considered extremely important. Despite the fact that she was bringing them up as Frenchwomen, in order to protect them from the conflict of choosing between their homelands, she hired a Polish governess so that Irène and Ève learned Polish. With some professors she knew from the Sorbonne, she set up a college for a group of their children, in which each scholar gave elementary lectures. The experimental teaching lasted two years and brought some good results: Skłodowska’s elder daughter easily passed her matriculation exam and went on to study at the Sorbonne. Eventually Irène Joliot-Curie followed in her parents' footsteps and became a physicochemist, and in 1935 she and her husband Frédéric Joliot-Curie were awarded the Nobel Prize for Chemistry.
In 1910, Skłodowska-Curie was due to be awarded the Legion of Honour, but she declined, as had her husband a few years earlier – both opposed to any honorary decoration. At the urging of her colleagues, however, she submitted her candidature to the Paris Academy of Sciences, which was expected to benefit her laboratory. Her candidature did not go through – the Academy was not yet ready to admit women.